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It's mostly water?
I don't have to heat up lemonade to make the sugar dissolve in it; why would tea be different?
Narrator: it's not different.
It isn't. If you have to heat the water to get sugar to dissolve in it 1) you have too much sugar and 2) when it cools again the sugar will prwcipitate out. It is easier and quicker to dissolve in hot water tho, so if you're impatient it may appear that the sugar won't dissolve in cold water.
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